Journal article · December 2024

Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics

I-Te Lu, Dongbin Shin, Mark Kamper Svendsen, Hannes Hübener, Umberto De Giovannini, Simone Latini, Michael Ruggenthaler and Angel Rubio

Proceedings of the National Academy of Sciences 121, e2415061121 (2024) · doi:10.1073/pnas.2415061121

Abstract

Strong laser pulses can control superconductivity, inducing non-equilibrium transient pairing by leveraging strong-light matter interaction. Here we demonstrate theoretically that equilibrium ground-state phonon-mediated superconductive pairing can be affected through the vacuum fluctuating electromagnetic field in a cavity. Using the recently developed ab initio quantum electrodynamical density-functional theory approximation, we specifically investigate the phonon-mediated superconductive behavior of MgB$_2$ under different cavity setups and find that in the strong light-matter coupling regime its superconducting transition temperature can be, in principles, enhanced by $\approx 73\%$ ($\approx 40\%$) in an in-plane (out-of-plane) polarized cavity. However, in a realistic cavity, we expect the T$_{\rm{c}}$ of MgB$_2$ can increase, at most, by $5$ K via photon vacuum fluctuations. The results highlight that strong light-matter coupling in extended systems can profoundly alter material properties in a non-perturbative way by modifying their electronic structure and phononic dispersion at the same time. Our findings indicate a pathway to the experimental realization of light-controlled superconductivity in solid-state materials at equilibrium via cavity-material engineering.

Cite

@article{Lu2024Cavity,
  author            = {I-Te Lu and Dongbin Shin and Mark Kamper Svendsen and Hannes Hübener and Umberto De Giovannini and Simone Latini and Michael Ruggenthaler and Angel Rubio},
  title             = {{Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics}},
  journal           = {Proceedings of the National Academy of Sciences},
  volume            = {121},
  number            = {50},
  pages             = {e2415061121},
  year              = {2024},
  month             = {dec},
  publisher         = {National Academy of Sciences},
  doi               = {10.1073/pnas.2415061121},
  eprint            = {2404.08122},
  archiveprefix     = {arXiv},
  primaryclass      = {cond-mat.supr-con},
  url               = {https://arxiv.org/abs/2404.08122},
  arxiv_journal_ref = {Proc. Natl. Acad. Sci. 121, e2415061121 (2024)},
}