Journal article · December 2024
Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics
Proceedings of the National Academy of Sciences 121, e2415061121 (2024) · doi:10.1073/pnas.2415061121
Abstract
Strong laser pulses can control superconductivity, inducing non-equilibrium transient pairing by leveraging strong-light matter interaction. Here we demonstrate theoretically that equilibrium ground-state phonon-mediated superconductive pairing can be affected through the vacuum fluctuating electromagnetic field in a cavity. Using the recently developed ab initio quantum electrodynamical density-functional theory approximation, we specifically investigate the phonon-mediated superconductive behavior of MgB$_2$ under different cavity setups and find that in the strong light-matter coupling regime its superconducting transition temperature can be, in principles, enhanced by $\approx 73\%$ ($\approx 40\%$) in an in-plane (out-of-plane) polarized cavity. However, in a realistic cavity, we expect the T$_{\rm{c}}$ of MgB$_2$ can increase, at most, by $5$ K via photon vacuum fluctuations. The results highlight that strong light-matter coupling in extended systems can profoundly alter material properties in a non-perturbative way by modifying their electronic structure and phononic dispersion at the same time. Our findings indicate a pathway to the experimental realization of light-controlled superconductivity in solid-state materials at equilibrium via cavity-material engineering.
Cite
@article{Lu2024Cavity,
author = {I-Te Lu and Dongbin Shin and Mark Kamper Svendsen and Hannes Hübener and Umberto De Giovannini and Simone Latini and Michael Ruggenthaler and Angel Rubio},
title = {{Cavity engineered phonon-mediated superconductivity in MgB$_2$ from first principles quantum electrodynamics}},
journal = {Proceedings of the National Academy of Sciences},
volume = {121},
number = {50},
pages = {e2415061121},
year = {2024},
month = {dec},
publisher = {National Academy of Sciences},
doi = {10.1073/pnas.2415061121},
eprint = {2404.08122},
archiveprefix = {arXiv},
primaryclass = {cond-mat.supr-con},
url = {https://arxiv.org/abs/2404.08122},
arxiv_journal_ref = {Proc. Natl. Acad. Sci. 121, e2415061121 (2024)},
}