Journal article · August 2026

Broken Detailed Balance and Entropy Production in CPTP Quantum Brownian Motion

Simone Artini, Gabriele Lo Monaco, Alberto Imparato, Mauro Paternostro and Sandro Donadi

Phys. Rev. Research 8, 033216 (2026) · doi:10.1103/qqxn-qc4g

Abstract

We rigorously analyze the non-equilibrium thermodynamic behavior of various formulations of quantum Brownian motion (QBM) using the framework of stochastic thermodynamics. While the widely used Caldeira-Leggett master equation exhibits desirable thermodynamic features, such as the fulfilment of a detailed balance, it fails to ensure complete positivity. In contrast, several completely positive and trace-preserving (CPTP) extensions turn out to be thermodynamically controversial. We show that such extensions introduce anomalous phase-space structures that violate detailed balance at the steady state, leading to non-vanishing entropy production and effective non-equilibrium current of unclear physical origins. Our results highlight a fundamental tension between quantum consistency and thermodynamic equilibration in open quantum systems.

Cite

@article{artini2026brokendetailedbalanceentropy,
 archiveprefix = {arXiv},
 author = {Artini, Simone and Lo Monaco, Gabriele and Imparato, Alberto and Paternostro, Mauro and Donadi, Sandro},
 doi = {10.1103/qqxn-qc4g},
 eprint = {2507.23322},
 journal = {Phys. Rev. Research},
 month = {Aug},
 number = {3},
 pages = {033216},
 publisher = {American Physical Society (APS)},
 title = {Broken Detailed Balance and Entropy Production in CPTP Quantum Brownian Motion},
 url = {https://doi.org/10.1103/qqxn-qc4g},
 volume = {8},
 year = {2026}
}